Just posted identical issue, almost 4 months after yours. I don't expect any replies since you've had none, so wondered if you were able to solve the problem?

cheers, Robert

MY POST:

CS5 crashes when attempting to print, os 10.9.4 Mavericks

This question is Not Answered.(Mark as assumed answered)

ROBERT HALLEWELL Sep 3, 2014 11:06 AM

Just a few days ago migrated from older iMac running 10.6.8 to new iMac running 10.9.4

I have the PS (and Indesign CS5) disc but am reluctant to attempt a reinstall, based on forum items where things were made worse

At the moment my work around is to print in Indesign.